Engineering

Carbon Nitride Nanosheet-based Titanium Dioxide Hybrid Photocatalyst for Organic Effluent Degradation

Authors

  • Ayesha Ashfaq

    The University of Lahore, Sargodha campus
    Author
  • Muhammad Tallal

    The University of Lahore, Sargodha campus
    Author
  • Amna Liaqat

    The University of Lahore, Sargodha campus
    Author
  • Nadia Khan

    The University of Lahore, Sargodha campus
    Author
  • Nouman Waheed

    The University of Lahore, Sargodha campus
    Author
  • Muhammad Amin

    The University of Lahore, Sargodha campus
    Author

DOI:

https://doi.org/10.71107/kx22gt91

Keywords:

Carbon nitride (g-C₃N₄); Titanium dioxide (TiO₂), Hybrid Nanocomposite, Hydrothermal synthesis, Photocatalytic wastewater treatment

Abstract

This research has synthesized and characterized a hybrid nanocomposite of carbon nitride (g-C₃N₄) nanosheets and titanium dioxide (TiO₂) for photocatalytic wastewater purification. The nanocomposite, designed with hydrothermal synthesis, was evaluated using UV-Vis spectroscopy, SEM, XRD, and FT-IR to identify its structural and optical properties. Photocatalytic activity was assessed using Congo red dye degradation, with efficiency tailored by altering temperature, time frame, and catalyst concentration. The results indicated successful hybridization, consistent shape, and improved degrading capability, indicating that the nanocomposite has the potential to treat wastewater sustainably.

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Author Biographies

  • Ayesha Ashfaq, The University of Lahore, Sargodha campus

    Ms. Ayesha is the MPhil research student at UOL

  • Muhammad Tallal, The University of Lahore, Sargodha campus

    Mr. Tallal is the mphil research student at UOL

  • Amna Liaqat, The University of Lahore, Sargodha campus

    Ms. Amna is the Lecturer at UOL

  • Nadia Khan, The University of Lahore, Sargodha campus

    Ms. Nadia is the lecturer at UOL

  • Nouman Waheed, The University of Lahore, Sargodha campus

    Mr. Nouman is the mphil research student at UOL

  • Muhammad Amin, The University of Lahore, Sargodha campus

    Dr. amin is the hod chemistry department at UOL

References

1. Jabeen, Nawishta, Ahmad Hussain, Muhammad Adnan Qaiser, Jazib Ali, Abdul Rehman, Nourreddine Sfina, Gharieb A. Ali, and Vineet Tirth. "Enhanced energy storage performance by relaxor highly entropic (Ba0.2Na0.2K0.2La0.2Bi0.2)TiO3 and (Ba0.2Na0.2K0.2Mg0.2Bi0.2)TiO3 ferroelectric ceramics." Applied Sciences 12, no. 24 (2022): 12933. https://doi.org/10.3390/app122412933 DOI: https://doi.org/10.3390/app122412933

2. Jabeen, N., Hussain, A., Elsaeedy, H. I., Rahman, A. U., & Tarique, M. (2023). Unique hierarchical architecture of SnO2 hexagonal interconnected nanolayered arrays as negative electrode for high performance asymmetric supercapacitors. Materials Chemistry and Physics, 303, 127796. https://doi.org/10.1016/j.matchemphys.2023.127796 DOI: https://doi.org/10.1016/j.matchemphys.2023.127796

3. Jabeen, N., Dahshan, A., Hegazy, H. H., Hussain, A., & ul Hassan, N. (2024). Hierarchical high K content birnessite MnO2 nanosheet arrays as high capacity cathode for asymmetric supercapacitor with broaden potential window of 2.6 V. Electrochimica Acta, 478, 143874. https://doi.org/10.1016/j.electacta.2024.143874 DOI: https://doi.org/10.1016/j.electacta.2024.143874

4. Bilińska, L., et al., Coupling of electrocoagulation and ozone treatment for textile wastewater reuse. Chemical Engineering Journal, 2019. 358: p. 992-1001. https://doi.org/10.1016/j.cej.2018.10.093 DOI: https://doi.org/10.1016/j.cej.2018.10.093

5. Chinnasamy, C., et al., Recent advancements in MXene-based nanocomposites as photocatalysts for hazardous pollutant degradation-A review. Environmental Research, 2023. 233: p. 116459. https://doi.org/10.1016/j.envres.2023.116459 DOI: https://doi.org/10.1016/j.envres.2023.116459

6. Behera, P., et al., MOF derived nano-materials: A recent progress in strategic fabrication, characterization and mechanistic insight towards divergent photocatalytic applications. Coordination Chemistry Reviews, 2022. 456: p. 214392. https://doi.org/10.1016/j.ccr.2021.214392 DOI: https://doi.org/10.1016/j.ccr.2021.214392

7. Darwesh, O.M., I.A. Matter, and M.F. Eida, Development of peroxidase enzyme immobilized magnetic nanoparticles for bioremediation of textile wastewater dye. Journal of Environmental Chemical Engineering, 2019. 7(1): p. 102805. https://doi.org/10.1016/j.jece.2018.11.049 DOI: https://doi.org/10.1016/j.jece.2018.11.049

8. Desa, A.L., et al., Industrial textile wastewater treatment via membrane photocatalytic reactor (MPR) in the presence of ZnO-PEG nanoparticles and tight ultrafiltration. Journal of Water Process Engineering, 2019. 31: p. 100872. https://doi.org/10.1016/j.jwpe.2019.100872 DOI: https://doi.org/10.1016/j.jwpe.2019.100872

9. Ji, D., et al., Preparation of high-flux PSF/GO loose nanofiltration hollow fiber membranes with dense-loose structure for treating textile wastewater. Chemical Engineering Journal, 2019. 363: p. 33-42. https://doi.org/10.1016/j.cej.2019.01.111 DOI: https://doi.org/10.1016/j.cej.2019.01.111

10. Leaper, S., et al., Air-gap membrane distillation as a one-step process for textile wastewater treatment. Chemical Engineering Journal, 2019. 360: p. 1330-1340. https://doi.org/10.1016/j.cej.2018.10.209 DOI: https://doi.org/10.1016/j.cej.2018.10.209

11. Li, S., et al., In vivo and in vitro efficient textile wastewater remediation by Aspergillus niger biosorbent. Nanoscale Advances, 2019. 1(1): p. 168-176. DOI: 10.1039/C8NA00132D DOI: https://doi.org/10.1039/C8NA00132D

12. Liu, Y., et al., Coagulation removal of Sb (V) from textile wastewater matrix with enhanced strategy: Comparison study and mechanism analysis. Chemosphere, 2019. 237: p. 124494. https://doi.org/10.1016/j.chemosphere.2019.124494 DOI: https://doi.org/10.1016/j.chemosphere.2019.124494

13. Lops, C., et al., Sonophotocatalytic degradation mechanisms of Rhodamine B dye via radicals generation by micro-and nano-particles of ZnO. Applied Catalysis B: Environmental, 2019. 243: p. 629-640. https://doi.org/10.1016/j.apcatb.2018.10.078 DOI: https://doi.org/10.1016/j.apcatb.2018.10.078

14. Mehrizad, A., et al., Sonocatalytic degradation of Acid Red 1 by sonochemically synthesized zinc sulfide-titanium dioxide nanotubes: Optimization, kinetics and thermodynamics studies. Journal of cleaner production, 2019. 215: p. 1341-1350. https://doi.org/10.1016/j.jclepro.2019.01.172 DOI: https://doi.org/10.1016/j.jclepro.2019.01.172

15. Mohammed, A., et al. COD removal from disperse blue dye 79 in wastewater by using Ozone-Fenton process. in IOP Conference Series: Materials Science and Engineering. 2019. IOP Publishing. DOI 10.1088/1757-899X/518/6/062015 DOI: https://doi.org/10.1088/1757-899X/518/6/062015

16. Nadeem, K., et al., Investigation of segregated wastewater streams reusability with membrane process for textile industry. Journal of Cleaner Production, 2019. 228: p. 1437-1445. https://doi.org/10.1016/j.jclepro.2019.04.205 DOI: https://doi.org/10.1016/j.jclepro.2019.04.205

17. Shaikh, B., et al., Mn3O4@ ZnO hybrid material: an excellent photocatalyst for the degradation of synthetic dyes including methylene blue, methyl orange and malachite green. Nanomaterials, 2022. 12(21): p. 3754. https://doi.org/10.3390/nano12213754 DOI: https://doi.org/10.3390/nano12213754

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Published

2025-04-30

Data Availability Statement

Data will be made available on request from Corresponding Author

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